First, the goods and manufacturers information
| Item Name: Diallylamine |
| Other names: Di-2-propenylamine |
| Suggestions for use and usage restrictions: / |
| Manufacturer or supplier name, address and telephone number: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: Diallylamine |
| Hazard classification and national or regional information: Product classification: Flash point flammable liquid in category 3.2 |
Global Harmonized System label elements, including precautionary statements:   Signal words: Hazardous Hazard Description: Flammable, toxic, can cause skin burns, and is highly irritating. Prevention : Respiratory protection: Wear a gas mask when the concentration in the air exceeds the standard. Air supply helmets are recommended for emergency rescue or evacuation. Eye protection: Wear chemical safety glasses. Body protection: Wear anti-corrosion overalls.Hand protection: Wear rubber gloves. Other: Minimize direct contact. Smoking, eating and drinking are strictly prohibited at the job site. After work, shower and change clothes. Reaction : Skin contact: Remove contaminated clothing and rinse thoroughly with plenty of running water for at least 15 minutes. Seek medical attention. Eye contact: Immediately open the upper and lower eyelids and rinse with running water or saline for at least 15 minutes. Seek medical attention. Inhalation: Remove quickly from the scene to fresh air. Keep the airway open. Give oxygen when breathing is difficult. Once breathing stops, begin CPR immediately. Seek medical attention. Ingestion: Inadvertently gargle, drink milk or egg white, and seek medical attention. Storage : Store in a cool, ventilated warehouse. Keep away from fire and heat. The temperature of the reservoir should not exceed 30 °C. It should be stored separately from oxidants, acids and food chemicals, and should not be mixed. Explosion-proof lighting and ventilation facilities are used. It is forbidden to use mechanical equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. Disposal : Refer to national and local regulations before disposal. It is recommended to use incineration. After mixing with the fuel, it is incinerated. The hydrogen halide discharged from the incinerator is removed by an acid scrubber. |
Third, the component identification data Pure substances:
| Chemical name: Diallylamine / |
| Common name: / |
| Chemical Abstracts Service Registration Number (CAS No.): 124-02-7 |
| Hazardous substance composition (percentage of ingredients): >99% |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, first aid measures
| First aid methods for different exposure routes: / |
| Inhalation: Remove quickly from the scene to fresh air. Keep the airway open. If breathing is difficult, give oxygen. If breathing stops, perform artificial respiration immediately. Seek medical attention. |
| Skin contact: Immediately remove contaminated clothing and rinse with plenty of running water for at least 15 minutes. Seek medical attention. . |
| Eye contact: Immediately lift eyelids and rinse thoroughly with plenty of running water or saline for at least 15 minutes. Seek medical attention. |
| Ingestion: Rinse mouth with water and drink milk or egg white. Seek medical attention. |
| The most important symptoms and dangerous effects: / |
| Protection that emergency personnel should take: / |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Fifith, Fire fighting measures
| Extinguishing media: water, water spray, anti-solvent foam, dry powder, carbon dioxide, sand. . |
| Hazardous characteristics: Its vapor and air can form an explosive mixture, which is easy to burn and explode in case of fire and high heat.Contact with oxidant reacts violently. It is easy to self-polymerize, and the polymerization reaction is rapidly increased as the temperature rises.Its vapor is heavier than air and can spread to a relatively distant place at a lower place. It will ignite and ignite in case of fire. In case of high heat, the internal pressure of the container increases, posing a risk of cracking and explosion. |
| Hazardous combustion products: carbon monoxide, carbon dioxide, nitrogen oxides. |
| Special Fire Fighting Procedures: Firefighters must wear a filter-type gas mask (full face mask) or an isolated respirator, wear a full-body fire-fighting anti-virus suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or produces sound from a safety relief device, it must be evacuated immediately. |
Sixth, leakage treatment method
| Quickly evacuate personnel from the contaminated area to a safe area, and conduct isolation to strictly restrict access. Cut off the fire source. It is recommended that emergency personnel wear self-contained positive pressure breathing apparatus and wear anti-virus suits. Cut off the source of the leak as much as possible. Prevent entry into restricted spaces such as sewers and flood drains. |
| Environmental precautions: / Cleaning methods and materials: Small spills: Mix with sand, dry lime or soda ash. It can also be rinsed with a large amount of water, diluted in water and placed in the wastewater system. A large number of leaks: building a dike or digging a pit. Transfer to a tank truck or special collector with a pump, recycle or transport to a waste disposal site for disposal. |
Seventh, Handling and storage
| Closed operation, pay attention to ventilation. Operators must be specially trained to strictly follow the operating procedures. Operators are advised to wear self-priming filter gas masks (half masks), chemical safety glasses, anti-poisoning overalls, and rubber-resistant gloves. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. Prevent vapors from leaking into the workplace air. Avoid contact with oxidants and acids. Lightly load and unload during handling to prevent damage to packaging and containers. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. Empty containers may be harmful residues |
| Store in a cool, ventilated warehouse. Keep away from fire and heat. The temperature of the reservoir should not exceed 30 °C. It should be stored separately from oxidants, acids and food chemicals, and should not be mixed. Explosion-proof lighting and ventilation facilities are used.It is forbidden to use mechanical equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Eighth, contact control / personal protection
| Engineering control: closed operation, pay attention to ventilation. |
| Respiratory protection: Self-priming filter respirators (half masks) must be worn when the concentration in the air exceeds the standard. Air respirators should be worn during emergency rescue or evacuation. |
| Eye protection: Wear chemical safety glasses. |
| Skin and body protection: Wear protective clothing to penetrate the overalls. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: Minimize direct contact. Smoking, eating and drinking are prohibited at the job site. After work, take a shower. |
Ninth, Physical and chemical properties
| Appearance (physical status, color, etc.) | Colorless liquid |
| odor | / |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | -88.4 / |
| Boiling point (°C) | 112 |
| Flash point (°C) | 1 5 |
| Evaporation rate | / |
| Flammability (solid, gaseous) | |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | / |
| Vapor density | 3.35 (relative vapour density, air = 1) |
| Relative density | 0.79 (water=1) |
| Solubility | Miscible with water, miscible in ethanol, ether, benzene. |
| Uses | Used in pharmaceutical, chemical synthesis, etc. |
Tenth, stability and reactivity
| Chemical stability: |
| Possibility of dangerous reactions: |
| Conditions to avoid (such as static unloading, shock or vibration): |
| Incompatible materials and materials: acids, acid chlorides, acid anhydrides, strong oxidizing agents. |
| Hazardous decomposition products: carbon monoxide, carbon dioxide, nitrogen oxides. |
Eleventh, Toxic information
| Exposure route: |
| Symptoms about physical, chemical and toxicological characteristics: |
| Chronic toxicity or long-term toxic effects: / |
| Quantitative measures of toxicity (eg acute toxicity estimates): LD50: 578 mg/kg (rat oral); 0.356 ml/Kg (rabbit percutaneous) LC50: >7000 ppm, 1 hour (rat inhalation); 27800 mg/m3 , 1 hour (rat inhalation) |
Twelveth, Ecological information
| Ecotoxicity: / |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Thirteen, Disposal methods : Refer to national and local regulations before disposal. It is recommended to use incineration. The nitrogen oxides emitted from the incinerator are removed by a scrubber.
Fourteen, Transportation information
| Dangerous Goods Code: 321 79 |
| UN number: 2359 |
| UN transport name: Diallylamine |
| Transport hazard categories: |
| Packing category: O52 |
| Packing method: ordinary wooden box outside the ampoule; threaded glass bottle, iron cover glass bottle, plastic bottle or metal barrel (can) outside the ordinary wooden box |
| Transportation precautions: Transportation vehicles should be equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is best to transport in the summer and evening. The tank (tank) used in transportation should have a grounding chain, and a hole partition can be arranged in the tank to reduce the static electricity generated by the shock. It is strictly forbidden to mix and transport with oxidants, acids, food chemicals, etc. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. The vehicle exhaust pipe carrying the item must be equipped with a fire-stop device, and it is forbidden to use the mechanical equipment and tools that are prone to sparks. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail.It is strictly forbidden to transport in bulk by wooden or cement vessels. |
Fifteen, Regulatory information
| Regulations on the Safety Management of Chemical Dangerous Goods (promulgated by the State Council on February 17, 1987), Regulations for the Administration of Safety Regulations for Chemical Dangerous Goods (Hua Fafa [1992] No. 677), Regulations on the Safe Use of Chemicals in the Workplace ([1996] Regulation No. 423), for the safe use, production, storage, transportation, loading and unloading of chemical dangerous goods, etc.; the classification and mark of commonly used dangerous chemicals (GB 13690-92) is classified as the 3.2th A flash point flammable liquid in the class. |
Sixteen, Other information
| references | / | |
| Tabulation unit | Name: Zouping Qili Additives Co., Ltd. | |
| Address / Phone: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China/0543-4788006 | ||
| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
